Photoinduced Reductive C–O Couplings from Unsymmetrical Bis-Cyclometalated Pt(IV) Dicarboxylato Complexes.
López-López, J. C.; Bautista, D.; González-Herrero, P. Inorg. Chem. 2025, 64, 662–673.
https://doi.org/10.1021/acs.inorgchem.4c03667
Synthesis, Luminescence, and Electrochemistry of Tris-Chelate Platinum(IV) Complexes with Cyclometalated N-Heterocyclic Carbene Ligands and Aromatic Diimines.
Serrano-Guarinos, J.; Jiménez-Garcia, A.; Bautista, D.; Vivancos, Á.; Gonzalez-Herrero, P. Inorg. Chem. 2024, 63, 24929–24939.
http://dx.doi.org/10.1021/acs.inorgchem.4c04446
Mechanochromic photoluminescence in a dinuclear alkynyl copper(I) complex with an extremely short Cu(I)⋯Cu(I) separation.
Moussa, J.; Juliá, F.; Chamoreau, L. M.; González-Herrero, P. New J. Chem. 2024, 48, 5577–5581.
https://doi.org/10.1039/D3NJ05209E
Luminescent Platinum(II) Complexes with Terdentate N∧C∧C Ligands.
Poveda, D.; Vivancos, Á.; Bautista, D.; González-Herrero, P. Inorg. Chem. 2023, 62, 20987–21002.
https://doi.org/10.1021/acs.inorgchem.3c02399
Photoinduced Reductive C–C and C–Heteroatom Couplings from Bis-cyclometalated Pt(IV) Alkynyl Complexes.
López-López, J. C; Bautista, D.; González-Herrero, P. Inorg. Chem. 2023, 62, 14411–14421.
https://doi.org/10.1021/acs.inorgchem.3c02162
Photochemically Induced Cyclometalations at Simple Platinum(II) Precursors.
Poveda, D.; Vivancos, Á.; Bautista, D.; González-Herrero, P. Inorg. Chem. 2023, 62, 6207–6213.
https://doi.org/10.1021/acs.inorgchem.3c00688
Reductive Elimination Reactions in Gold(III) Complexes Leading to C(sp3)–X (X = C, N, P, O, Halogen) Bond Formation: Inner-Sphere vs SN2 Pathways.
Portugués, A.; Martínez-Nortes, M. Á.; Bautista, D.; González-Herrero, P.; Gil-Rubio, J. Inorg. Chem. 2023, 62, 1708–1718.
https://doi.org/10.1021/acs.inorgchem.2c04166
Phosphorescent Tris-Cyclometalated Pt(IV) Complexes with Mesoionic N-Heterocyclic Carbene and 2-Arylpyridine Ligands.
Vivancos, Á.; Bautista, D.; González-Herrero, P. Inorg. Chem. 2022, 61, 12033–12042.
https://doi.org/10.1021/acs.inorgchem.2c02039
Phosphorescent biaryl platinum(IV) complexes obtained through double metalation of dibenzoiodolium ions
López-López, J. C.; Bautista, D.; González-Herrero, P. Chem. Commun. 2022, 58, 4532–4535.
https://doi.org/10.1039/D2CC01018F
Luminescent halido(aryl) Pt(IV) complexes obtained via oxidative addition of iodobenzene or diaryliodonium salts to bis-cyclometalated Pt(II) precursors
López-López, J. C., Bautista, D.; González-Herrero, P. Dalton Trans., 2021, 50, 13294–13305.
https://doi.org/10.1039/D1DT02349G
Strongly Luminescent Pt(IV) Complexes with a Mesoionic N-Heterocyclic Carbene Ligand: Tuning Their Photophysical Properties
Vivancos, Á.; Jiménez-García, A.; Bautista, D.; González-Herrero, P. Inorg. Chem., 2021, 60, 7900–7913.
https://doi.org/10.1021/acs.inorgchem.1c00410
Visible light driven generation and alkyne insertion reactions of stable bis-cyclometalated Pt(IV) hydrides
Poveda, D.; Vivancos, Á.; Bautista, D.; González-Herrero, P. Chem. Sci. 2020, 11, 12095-12102.
https://doi.org/10.1039/D0SC04879H
Stereoselective Formation of Facial Tris‐Cyclometalated Pt(IV) Complexes: Dual Phosphorescence from Heteroleptic Derivatives
López‐López, J. C.; Bautista, D.; González‐Herrero, P. Chem. Eur. J. 2020, 26, 11307-11315.
https://doi.org/10.1002/chem.202001164
Metalated Ir–CNP Complexes Containing Imidazolin‐2‐ylidene and Imidazolidin‐2‐ylidene Donors – Synthesis, Structure, Luminescence, and Metal–Ligand Cooperative Reactivity
Hernández‐Juárez, M.; Sánchez, P.; López‐Serrano, J.; Lara, P.; González‐Herrero, P.; Rendón, N.; Álvarez, E.; Paneque, M.; Suárez, A. Eur. J. Inorg. Chem. 2020, 3944–3953.
https://doi.org/10.1002/ejic.202000681
Selective synthesis, reactivity and luminescence of unsymmetrical bis-cyclometalated Pt(IV) complexes
Vivancos, Á.; Poveda, D.; Muñoz, A.; Moreno, J.; Bautista, D.; González-Herrero, P. Dalton Trans. 2019, 48, 14367-14382.
https://doi.org/10.1039/c9dt02431j
Luminescent Platinum(IV) Complexes Bearing Cyclometalated 1,2,3-Triazolylidene and Bi- or Terdentate 2,6-Diarylpyridine Ligands
Vivancos, Á.; Bautista, D.; González-Herrero, P. Chem. Eur. J. 2019, 25, 6014-6025.
https://doi.org/10.1002/chem.201900489
Hydrogenation of an iridium-coordinated imidazol-2-ylidene ligand fragment
Hernández-Juárez, M.; López-Serrano, J.; González-Herrero, P.; Rendón, N.; Álvarez, E.; Paneque, M.; P. ; Suárez, A. Chem. Commun. 2018, 54, 3843-3846.
https://doi.org/10.1039/c8cc00420j
Influence of Ancillary Ligands and Isomerism on the Luminescence of Bis-cyclometalated Platinum(IV) Complexes
Juliá, F.; García-Legaz, M.-D., Bautista, D; González-Herrero, P. Inorg. Chem. 2016, 55, 7647–7660.
http://dx.doi.org/10.1021/acs.inorgchem.6b01100
Spotlight on the ligand: luminescent cyclometalated Pt(IV) complexes containing a fluorenyl moiety
Juliá, F.; González-Herrero, P. Dalton Trans. 2016, 45, 10599-10608.
http://dx.doi.org/10.1039/c6dt01722c
Aromatic C-H Activation in the Triplet Excited State of Cyclometalated Platinum(II) Complexes Using Visible Light
Juliá, F.; González-Herrero, P. J. Am. Chem. Soc. 2016, 138, 5276-5282.
http://dx.doi.org/10.1021/jacs.5b13311
Developing strongly luminescent platinum(IV) complexes: facile synthesis of bis-cyclometalated neutral emitters
Juliá, F.; Bautista, D.; González-Herrero, P. Chem. Commun. 2016, 52, 1657-1660.
http://dx.doi.org/10.1039/c5cc09566b
Exploring Excited-State Tunability in Luminescent Tris-cyclometalated Platinum(IV) Complexes: Synthesis of Heteroleptic Derivatives and Computational Calculations
Juliá, F.; Aullón, G.; Bautista, D.; González-Herrero, P. Chem. Eur. J. 2014, 20, 17346-17359.
http://dx.doi.org/10.1002/chem.201404583
Homoleptic tris-cyclometalated platinum(IV) complexes: a new class of long-lived, highly efficient 3LC emitters
Juliá, F.; Bautista, D.; Fernández-Hernández, J. M.; González-Herrero, P. Chem. Sci. 2014, 5, 1875-1880.
http://dx.doi.org/10.1039/c3sc53187b
Reactivity of Ortho-Palladated Benzamides toward CO, Isocyanides, and Alkynes. Synthesis of Functionalized Isoindolin-1-ones and 4,5-Disubstituted Benzo[c]azepine-1,3-diones
Frutos-Pedreño, R.; González-Herrero, P.; Vicente, J.; Jones, P. G. Organometallics 2013, 32, 4664-4676.
http://dx.doi.org/10.1021/om4006406
Synthesis and Reactivity of Ortho-Palladated 3-Phenylpropanamides. Insertion of CO, XyNC, and Alkynes into the Pd-C Bond. Synthesis of Seven- and Nine-Membered Palladacycles and Benzazepine- and Benzazonine-Based Heterocycles
Frutos-Pedreño, R.; González-Herrero, P.; Vicente, J.; Jones, P. G. Organometallics 2013, 32, 1892-1904.
http://dx.doi.org/10.1021/om4000192
Sequential Insertion of Alkynes and CO or Isocyanides into the Pd-C Bond of Cyclopalladated Phenylacetamides. Synthesis of Eight-Membered Palladacycles, Benzo[d]azocine-2,4(1H,3H)-diones, and Highly Functionalized Acrylonitrile and Acrylamide Derivatives
Frutos-Pedreño, R.; González-Herrero, P.; Vicente, J.; Jones, P. G. Organometallics 2012, 31, 3361-3372.
http://dx.doi.org/10.1021/om300151n
Synthesis and Photophysical Properties of Cyclometalated Platinum(II) 1,2-Benzenedithiolate Complexes and Heterometallic Derivatives Obtained from the Addition of [Au(PCy3)]+ Units
Juliá, F.; Jones, P. G.; González-Herrero, P. Inorg. Chem. 2012, 51, 5037-5049.
http://dx.doi.org/10.1021/ic202465k
Synthesis and Reactivity of Ortho-Palladated Phenylacetamides. Intramolecular C-N vs C-O Reductive Coupling after CO or XyNC Insertion into the Pd-C Bond. Synthesis of Isoquinoline- and Isocoumarin-Based Heterocycles
Vicente, J.; González-Herrero, P.; Frutos-Pedreño, R.; Chicote, M.-T.; Jones, P. G.; Bautista, D. Organometallics 2011, 30, 1079-1093.
http://dx.doi.org/10.1021/om101110s
Novel Types of Tetra-, Hexa-, Octa-, and Dodecanuclear Silver Clusters Containing (2,7-Di-tert-butylfluoren-9-ylidene)methanedithiolate
Vicente, J.; González-Herrero, P.; García-Sánchez, Y.; Jones, P. G. Inorg. Chem. 2009, 48, 2060-2071.
http://dx.doi.org/10.1021/ic802045j
Dinuclear Copper(I) and Copper(I)/Silver(I) Complexes with Condensed Dithiolato Ligands
Vicente, J.; González-Herrero, P.; García-Sánchez, Y.; Bautista, D. Inorg. Chem. 2008, 47, 10662-10673.
http://dx.doi.org/10.1021/ic8014139
Synthesis, Structure, and Luminescence of Di- and Trinuclear Palladium/Gold and Platinum/Gold Complexes with (2,7-Di-tert-butylfluoren-9-ylidene)methanedithiolate
Vicente, J.; González-Herrero, P.; Pérez-Cadenas, M.; Jones, P. G.; Bautista, D. Inorg. Chem. 2007, 46, 4718-4732.
http://dx.doi.org/10.1021/ic070164h
Copper Complexes with (2,7-Di-tert-butylfluoren-9-ylidene)methanedithiolate: Oxidatively Promoted Dithioate Condensation
Vicente, J.; González-Herrero, P.; García-Sánchez, Y.; Jones, P. G.; Bautista, D. Eur. J. Inorg. Chem. 2006, 115-126.
http://dx.doi.org/10.1002/ejic.200500613
(Fluoren-9-ylidene)methanedithiolato Complexes of Platinum: Synthesis, Reactivity, and Luminescence
Vicente, J.; González-Herrero, P.; Pérez-Cadenas, M.; Jones, P. G.; Bautista, D. Inorg. Chem. 2005, 44, 7200-7213.
http://dx.doi.org/10.1021/ic050748o
(Fluoren-9-ylidene)methanedithiolato Complexes of Gold: Synthesis, Luminescence, and Charge-Transfer Adducts
Vicente, J.; González-Herrero, P.; García-Sánchez, Y.; Jones, P. G.; Bardají, M. Inorg. Chem. 2004, 43, 7516-7531.
http://dx.doi.org/10.1021/ic049132+
9H-Fluorene-9-carbodithioic acids and dithioates. First isolation and characterization of a gem-enedithiol
Vicente, J.; González-Herrero, P.; García-Sánchez, Y.; Pérez-Cadenas, M. Tetrahedron Lett. 2004, 45, 8859-8861.
http://dx.doi.org/10.1016/j.tetlet.2004.09.180
Vinylidene, Vinyl, and Carbene Ruthenium Complexes with Chelating Diphosphanes as Ligands
Werner, H.; Jung, S.; González-Herrero, P.; Ilg, K.; Wolf, J. Eur. J. Inorg. Chem. 2001, 1957-1961.
https://doi.org/10.1002/1099-0682(200108)2001:8<1957::AID-EJIC1957>3.0.CO;2-E
The Sensitive Balance between Five-Coordinate Carbene and Six-Coordinate Carbyne Ruthenium Complexes Formed from Ruthenium Vinylidene Precursors
González-Herrero, P.; Weberndörfer, B.; Ilg, K.; Wolf, J.; Werner, H. Organometallics 2001, 20, 3672-3685.
http://dx.doi.org/10.1021/om010422x
The First Example of an Equilibrium between a Carbene and an Isomeric Carbyne Transition Metal Complex
González-Herrero, P.; Weberndörfer, B.; Ilg, K.; Wolf, J.; Werner, H. Angew. Chem. Int. Ed. 2000, 39, 3266-3269.
http://dx.doi.org/10.1002/1521-3773(20000915)39:18<3266::aid-anie3266>3.0.co;2-#
Complexes with S-Donor Ligands. 7. New 1,1-Ethylenedithiolato Complexes of Thallium(I), Gold(I), and Gold(III): Syntheses, Structure, and Molecular Cubic Hyperpolarizabilities
Vicente, J.; Chicote, M. T.; González-Herrero, P.; Jones, P. G.; Humphrey, M. G.; Cifuentes, M. P.; Samoc, M.; Luther-Davies, B. Inorg. Chem. 1999, 38, 5018-5026.
http://dx.doi.org/10.1021/ic990379u
Recent Advances in the Chemistry of Gold(I) Complexes with C-, N- and S-Donor Ligands Part I: Alkynyl, Amino, Imino and Nitrido Derivatives
Vicente, J.; Chicote, M. T.; Abrisqueta, M. D.; González-Herrero, P.; Guerrero, R. Gold Bull. 1998, 31, 83-87.
http://dx.doi.org/10.1007/BF03214767
Recent Advances in the Chemistry of Gold(I) Complexes with C-, N- and S-Donor Ligands Part II: Sulfur Ylide, Hydrosulfido, Sulfido, Trithiocarbonato, Dithiocarbimato and 1,1-Ethylenedithiolato Derivatives
Vicente, J.; Chicote, M. T.; Abrisqueta, M. D.; González-Herrero, P.; Guerrero, R. Gold Bull. 1998, 31, 126-130.
http://dx.doi.org/10.1007/BF03214777
Complexes with S-Donor Ligands. 6. Synthesis of the First Family of (Trithiocarbonato)gold Complexes. Crystal Structure of [(PPh3)2N][AuCl2(CS3)]
Vicente, J.; Chicote, M. T.; González-Herrero, P.; Jones, P. G. Inorg. Chem. 1997, 36, 5735-5739.
http://dx.doi.org/10.1021/ic970478c
CS2 insertion into a gold-carbon bond. First syntheses and characterization of 2,2-diacetylethylene-1,1-dithiolato complexes. Crystal structure of [N(PPh3)2][Au{η2-S2C=C(COMe)2}2]
Vicente, J.; Chicote, M. T.; González-Herrero, P.; Jones, P. G. J. Chem. Soc., Chem. Commun. 1997, 2047-2048.
http://dx.doi.org/10.1039/a705052f
Complexes with S-Donor Ligands. 5. Syntheses of the First (Hydrosulfido)- and Anionic Sulfidoorganogold(I) complexes. Crystal and Molecular Structure of (Et4N)2[{Au(C6F5)}3(µ3-S)]·0.5MeC(O)Et
Vicente, J.; Chicote, M. T.; González-Herrero, P.; Grünwald, C.; Jones, P. G. Organometallics 1997, 16, 3381-3387.
http://dx.doi.org/10.1021/om970106b
Five-Coordinate 16-Electron Carbene- and Vinylideneruthenium(II) Complexes Prepared from [RuCl2(C8H12)]n or from the New Dihydridoruthenium(IV) Compound [RuH2Cl2(PiPr3)2]
Grünwald, C.; Gevert, O.; Wolf, J.; González-Herrero, P.; Werner, H. Organometallics 1996, 15, 1960-1962.
http://dx.doi.org/10.1021/om9509554
Synthesis of the First Trithiocarbonatogold Complex: [N(PPh3)2]2[Au2(µ2-η2-CS3)2]. First Crystal Structure of a µ2-η2-Bridging Trithiocarbonato Complex
Vicente, J.; Chicote, M. T.; González-Herrero, P.; Jones, P. G. J. Chem. Soc., Chem. Commun. 1995, 745-746.
http://dx.doi.org/10.1039/c39950000745
Complexes with S-Donor Ligands. Part 2. Synthesis of Anionic Bis(thiolato)gold(I) Complexes. Crystal-Structure of [N(PPh3)2][Au(SR)2] (R = Benzoxazol-2-yl)
Vicente, J.; Chicote, M. T.; González-Herrero, P.; Jones, P. G. J. Chem. Soc., Dalton Trans. 1994, 3183-3187.
http://dx.doi.org/10.1039/dt9940003183
A Postulated Carrier of Gold in Hydrothermal Ore Solutions: Synthesis and Crystal Structure of [(Ph3P)2N][Au(SH)2], the First Homoleptic Hydrogensulfido Complex
Vicente, J.; Chicote, M. T.; González-Herrero, P.; Jones, P. G.; Ahrens, B. Angew. Chem., Int. Ed. Engl. 1994, 33, 1852-1853.